Try this:
With xlApp.ActiveSheet.Pictures.Insert(PicPath)
With .ShapeRange
.LockAspectRatio = msoTrue
.Width = 75
.Height = 100
End With
.Left = xlApp.ActiveSheet.Cells(i, 20).Left
.Top = xlApp.ActiveSheet.Cells(i, 20).Top
.Placement = 1
.PrintObject = True
End With
It's better not to .select anything in Excel, it is usually never necessary and slows down your code.