Just assign row to a particular index, using loc
:
df.loc[-1] = [2, 3, 4] # adding a row
df.index = df.index + 1 # shifting index
df = df.sort_index() # sorting by index
And you get, as desired:
A B C
0 2 3 4
1 5 6 7
2 7 8 9
See in Pandas documentation Indexing: Setting with enlargement.