Beyond historical (good and already reported) reasons, there's is also a little problem with operators precedence: dot operator has higher priority than star operator, so if you have struct containing pointer to struct containing pointer to struct... These two are equivalent:
(*(*(*a).b).c).d
a->b->c->d
But the second is clearly more readable. Arrow operator has the highest priority (just as dot) and associates left to right. I think this is clearer than use dot operator both for pointers to struct and struct, because we know the type from the expression without have to look at the declaration, that could even be in another file.