leading 0
means this is octal constant, not the decimal one. and you need an octal to change file mode.
permissions are a bit mask, for example, rwxrwx---
is 111111000
in binary, and it's very easy to group bits by 3 to convert to the octal, than calculate the decimal representation.
0644
(octal) is 0.110.100.100
in binary (i've added dots for readability), or, as you may calculate, 420
in decimal.