16 is severity and 1 is state, more specifically following example might give you more detail on syntax and usage:
BEGIN TRY
-- RAISERROR with severity 11-19 will cause execution to
-- jump to the CATCH block.
RAISERROR ('Error raised in TRY block.', -- Message text.
16, -- Severity.
1 -- State.
);
END TRY
BEGIN CATCH
DECLARE @ErrorMessage NVARCHAR(4000);
DECLARE @ErrorSeverity INT;
DECLARE @ErrorState INT;
SELECT
@ErrorMessage = ERROR_MESSAGE(),
@ErrorSeverity = ERROR_SEVERITY(),
@ErrorState = ERROR_STATE();
-- Use RAISERROR inside the CATCH block to return error
-- information about the original error that caused
-- execution to jump to the CATCH block.
RAISERROR (@ErrorMessage, -- Message text.
@ErrorSeverity, -- Severity.
@ErrorState -- State.
);
END CATCH;
You can follow and try out more examples from http://msdn.microsoft.com/en-us/library/ms178592.aspx