[python] Constructing pandas DataFrame from values in variables gives "ValueError: If using all scalar values, you must pass an index"

Change your 'a' and 'b' values to a list, as follows:

a = [2]
b = [3]

then execute the same code as follows:

df2 = pd.DataFrame({'A':a,'B':b})
df2

and you'll get:

    A   B
0   2   3

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