"most convenient block of data" probably refers to the width (in bits) of the WORD, in correspondance to the system bus width, or whatever underlying "bandwidth" is available. On a 16 bit system, with WORD being defined as 16 bits wide, moving data around in chunks the size of a WORD will be the most efficient way. (On hardware or "system" level.)
With Java being more or less platform independant, it just defines a "WORD" as the next size from a "BYTE", meaning "full bandwidth". I guess any platform that's able to run Java will use 32 bits for a WORD.