The sizeof the structure should be 8 bytes on a 32 bit system, so that the size of the structure becomes multiple of 2. This makes individual structures available at the correct byte boundaries when an array of structures is declared. This is achieved by padding the structure with 3 bytes at the end.
If the structure had the pointer declared after the char, it would still be 8 bytes in size but the 3 byte padding would have been added to keep the pointer (which is a 4 byte element) aligned at a 4 byte address boundary.
The rule of thumb is that elements should be at an offset which is the multiple of their byte size and the structure itself should be of a size which is a multiple of 2.