%TIME% is in the format H:MM:SS,CS after midnight and hence conversion to centiseconds >doesn't work. Seeing Patrick Cuff's post with 6:46am it seems that it is not only me.
But with this lines bevor you should will fix that problem easy:
if " "=="%StartZeit:~0,1%" set StartZeit=0%StartZeit:~-10%
if " "=="%EndZeit:~0,1%" set EndZeit=0%EndZeit:~-10%
Thanks for your nice inspiration! I like to use it in my mplayer, ffmpeg, sox Scripts to pimp my mediafiles for old PocketPlayers just for fun.