mbstring is a "non-default" extension, that is not enabled by default ; see this page of the manual :
Installation
mbstring is a non-default extension. This means it is not enabled by default. You must explicitly enable the module with the configure option. See the Install section for details
So, you might have to enable that extension, modifying the php.ini file (and restarting Apache, so your modification is taken into account)
I don't use CentOS, but you may have to install the extension first, using something like this (see this page, for instance, which seems to give a solution) :
yum install php-mbstring
(The package name might be a bit different ; so, use yum search to get it :-) )