This works in rails 3.1:
in config/environment.rb (or in config/environments/.. to target a specific environment) :
YourApp::Application.config.yourKey = 'foo'
This will be accessible in controller or views like this:
YourApp::Application.config.yourKey
(YourApp should be replaced by your application name.)
Note: It's Ruby code, so if you have a lot of config keys, you can do this :
in config/environment.rb :
YourApp::Application.configure do
config.something = foo
config.....
config....
.
config....
end