Here is another way of doing this for pyspark:
#import concat and lit functions from pyspark.sql.functions
from pyspark.sql.functions import concat, lit
#Create your data frame
countryDF = sqlContext.createDataFrame([('Ethiopia',), ('Kenya',), ('Uganda',), ('Rwanda',)], ['East Africa'])
#Use select, concat, and lit functions to do the concatenation
personDF = countryDF.select(concat(countryDF['East Africa'], lit('n')).alias('East African'))
#Show the new data frame
personDF.show()
----------RESULT-------------------------
84
+------------+
|East African|
+------------+
| Ethiopian|
| Kenyan|
| Ugandan|
| Rwandan|
+------------+