The following works fine for me in Excel 2007. It is simple, and performs a full copy (retains all formatting, etc.):
Sheets("Sheet1").Columns(1).Copy Destination:=Sheets("Sheet2").Columns(2)
"Columns" returns a Range object, and so this is utilizing the "Range.Copy" method. "Destination" is an option to this method - if not provided the default is to copy to the paste buffer. But when provided, it is an easy way to copy.
As when manually copying items in Excel, the size and geometry of the destination must support the range being copied.