To discover any constraints used, use the code below:
-- Set the long data type for display purposes to 500000.
SET LONG 500000
-- Define a session scope variable.
VARIABLE output CLOB
-- Query the table definition through the <code>DBMS_METADATA</code> package.
SELECT dbms_metadata.get_ddl('TABLE','[Table Described]') INTO :output FROM dual;
This essentially shows a create statement for how the referenced table is made. By knowing how the table is created, you can see all of the table constraints.
Answer taken from Michael McLaughlin's blog: http://michaelmclaughlin.info/db1/lesson-5-querying-data/lab-5-querying-data/ From his Database Design I class.