You can do this by casting the dict keys and values to list. It can also be be done for items.
Example:
f = {'one': 'police', 'two': 'oranges', 'three': 'car'}
list(f.keys())[0] = 'one'
list(f.keys())[1] = 'two'
list(f.values())[0] = 'police'
list(f.values())[1] = 'oranges'