Facebook uses the LAMP stack, so if you want to get a career with them you're going to want to focus on that. In addition they often have C++ and/or Java listed in their requirements as well.
One of the postings includes the following requirements:
Another:
Another:
http://www.facebook.com/careers/#!/careers/department.php?dept=engineering
Also, do any other social networking sites use the same language?
Some other companys that use PHP/LAMP Stack: