When you want to access an element, you have to first dereference your pointer, and then index the element you want (which is also dereferncing). i.e. you need to do:
printf("\nvalue:%c", (*ptr)[0]);
, which is the same as *((*ptr)+0)
Note that working with pointer to arrays are not very common in C. instead, one just use a pointer to the first element in an array, and either deal with the length as a separate element, or place a senitel value at the end of the array, so one can learn when the array ends, e.g.
char arr[5] = {'a','b','c','d','e',0};
char *ptr = arr; //same as char *ptr = &arr[0]
printf("\nvalue:%c", ptr[0]);