In NumPy it is quite simple
import numpy as np
P=2.45
S=[22, 33, 45.6, 21.6, 51.8]
SP = P*np.array(S)
I recommend taking a look at the NumPy tutorial for an explanation of the full capabilities of NumPy's arrays:
https://scipy.github.io/old-wiki/pages/Tentative_NumPy_Tutorial