There is a rule in Python programming called "it is Easier to Ask for Forgiveness than for Permission" (in short: EAFP). It means that you should catch exceptions instead of checking values for validity.
Thus, try the following:
try:
qByUser = byUsrUrlObj.read()
qUserData = json.loads(qByUser).decode('utf-8')
questionSubjs = qUserData["all"]["questions"]
except ValueError: # includes simplejson.decoder.JSONDecodeError
print 'Decoding JSON has failed'
EDIT: Since simplejson.decoder.JSONDecodeError
actually inherits from ValueError
(proof here), I simplified the catch statement by just using ValueError
.