Just simply use isset($_POST['radio']) so that whenever i click any of the radio button, the one that is clicked is set to the post.
<form method="post" action="sample.php">
select sex:
<input type="radio" name="radio" value="male">
<input type="radio" name="radio" value="female">
<input type="submit" value="submit">
</form>
<?php
if (isset($_POST['radio'])){
$Sex = $_POST['radio'];
}
?>