Just use IDA PRO (https://www.hex-rays.com/products/ida/index.shtml) to disassemble the file, and search for some known command line option (using Search...Text) - in that section you will then typically see all the command line options - for the program (LIB2NIST.exe) in the screenshot below, for example, it shows a documented command line option (/COM2TAG) but also some undocumented ones, like /L. Hope this helps?