Building on the Python 2 solution from @GarethLatty, the following is a way to get a single line equivalent without intermediate variables in Python 2.
t=iter([1, 1, 2, 3, 5, 8, 13, 21, 34, 55]);h,t = [(h,list(t)) for h in t][0]
If you need it to be exception-proof (i.e. supporting empty list), then add:
t=iter([]);h,t = ([(h,list(t)) for h in t]+[(None,[])])[0]
If you want to do it without the semicolon, use:
h,t = ([(h,list(t)) for t in [iter([1,2,3,4])] for h in t]+[(None,[])])[0]