[php] php.ini: which one?

Although Pascal's answer was detailed and informative it failed to mention some key information in the assumption that everyone knows how to use phpinfo()

For those that don't:

Navigate to your webservers root folder such as /var/www/

Within this folder create a text file called info.php

Edit the file and type phpinfo()

Navigate to the file such as: http://www.example.com/info.php

Here you will see the php.ini path under Loaded Configuration File:

phpinfo

Make sure you delete info.php when you are done.