Without a backslash, special characters have a natural special meaning. With a backslash they print as they appear.
\ - escape the next character
" - start or end of string
’ - start or end a character constant
% - start a format specification
\\ - print a backslash
\" - print a double quote
\’ - print a single quote
%% - print a percent sign
The statement
printf(" \" ");
will print you the quotes. You can also print these special characters \a, \b, \f, \n, \r, \t and \v with a (slash) preceeding it.