From the documentation for FirstOrDefault
[Returns] default(TSource) if source is empty;
From the documentation for default(T):
the default keyword, which will return null for reference types and zero for numeric value types. For structs, it will return each member of the struct initialized to zero or null depending on whether they are value or reference types. For nullable value types, default returns a System.Nullable, which is initialized like any struct.
Therefore, the default value can be null or 0 depending on whether the type is a reference or value type, but you cannot control the default behaviour.