To call a sub inside another sub you only need to do:
Call Subname()
So where you have CalculateA(Nc,kij, xi, a1, a)
you need to have call CalculateA(Nc,kij, xi, a1, a)
As the which runs first problem it's for you to decide, when you want to run a sub you can go to the macro list select the one you want to run and run it, you can also give it a key shortcut, therefore you will only have to press those keys to run it. Although, on secondary subs, I usually do it as Private sub CalculateA(...)
cause this way it does not appear in the macro list and it's easier to work
Hope it helps, Bruno
PS: If you have any other question just ask, but this isn't a community where you ask for code, you come here with a question or a code that isn't running and ask for help, not like you did "It would be great if you could write it in the Excel VBA format."