You can find the Python executable with this command:
C:\> where python.exe
It should return something like:
C:\Users\<user>\AppData\Local\enthought\Canopy32\User\python.exe
Open regedit, navigate to HKEY_CURRENT_USER\SOFTWARE\Python\PythonCore\<version>\PythonPath
and add or edit the default key with this the value found in the first command.
Logout, login and python should be found. SciKit can now be installed.
See Additional “application paths” in https://docs.python.org/2/using/windows.html#finding-modules for more details.