In the value or values you want to separate, enter the =NA() formula. This will appear that the value is skipped but the preceding and following data points will be joined by the series line.
Enter the data you want to skip in the same location as the original (row or column) but add it as a new series. Add the new series to your chart.
Format the new data point to match the original series format (color, shape, etc.). It will appear as though the data point was just skipped in the original series but will still show on your chart if you want to label it or add a callout.