Try this
function readRows() {
var sheet = SpreadsheetApp.getActiveSheet();
var rows = sheet.getDataRange();
var numRows = rows.getNumRows();
//var values = rows.getValues();
var Names = sheet.getRange("A2:A7");
var Name = [
Names.getCell(1, 1).getValue(),
Names.getCell(2, 1).getValue(),
.....
Names.getCell(5, 1).getValue()]
You can define arrays simply as follows, instead of allocating and then assigning.
var arr = [1,2,3,5]
Your initial error was because of the following line, and ones like it
var Name[0] = Name_cell.getValue();
Since Name is already defined and you are assigning the values to its elements, you should skip the var, so just
Name[0] = Name_cell.getValue();
Pro tip: For most issues that, like this one, don't directly involve Google services, you are better off Googling for the way to do it in javascript in general.