This should do it. You were missing a ) and you only need """ not 4 of them. Also you don't need a elif at the end.
ans=True
while ans:
print("""
1.Add a Student
2.Delete a Student
3.Look Up Student Record
4.Exit/Quit
""")
ans=raw_input("What would you like to do? ")
if ans=="1":
print("\nStudent Added")
elif ans=="2":
print("\n Student Deleted")
elif ans=="3":
print("\n Student Record Found")
elif ans=="4":
print("\n Goodbye")
ans = None
else:
print("\n Not Valid Choice Try again")