There were just a couple of minor amendments required:
ans=True
while ans:
print ("""
1.Add a Student
2.Delete a Student
3.Look Up Student Record
4.Exit/Quit
""")
ans=raw_input("What would you like to do? ")
if ans=="1":
print("\n Student Added")
elif ans=="2":
print("\n Student Deleted")
elif ans=="3":
print("\n Student Record Found")
elif ans=="4":
print("\n Goodbye")
elif ans !="":
print("\n Not Valid Choice Try again")
I have changed the four quotes to three (this is the number required for multiline quotes), added a closing bracket after "What would you like to do? "
and changed input to raw_input.