SyntaxFix

[r] The condition has length > 1 and only the first element will be used

Like sgibb said it was an if problem, it had nothing to do with | or ||.

Here is another way to solve your problem:

for (i in 1:nrow(trip)) {
  if(trip$Ref.y[i]=='G' & trip$Variant.y[i]=='T'|trip$Ref.y[i]=='C' & trip$Variant.y[i]=='A') {
    trip[i, 'mutType'] <- "G:C to T:A"
  }
  else if(trip$Ref.y[i]=='G' & trip$Variant.y[i]=='C'|trip$Ref.y[i]=='C' & trip$Variant.y[i]=='G') {
    trip[i, 'mutType'] <- "G:C to C:G"
  }
  else if(trip$Ref.y[i]=='G' & trip$Variant.y[i]=='A'|trip$Ref.y[i]=='C' & trip$Variant.y[i]=='T') {
    trip[i, 'mutType'] <- "G:C to A:T"
  }
  else if(trip$Ref.y[i]=='A' & trip$Variant.y[i]=='T'|trip$Ref.y[i]=='T' & trip$Variant.y[i]=='A') {
    trip[i, 'mutType'] <- "A:T to T:A"
  }
  else if(trip$Ref.y[i]=='A' & trip$Variant.y[i]=='G'|trip$Ref.y[i]=='T' & trip$Variant.y[i]=='C') {
    trip[i, 'mutType'] <- "A:T to G:C"
  }
  else if(trip$Ref.y[i]=='A' & trip$Variant.y[i]=='C'|trip$Ref.y[i]=='T' & trip$Variant.y[i]=='G') {
    trip[i, 'mutType'] <- "A:T to C:G"
  }
}

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