You can execute:
$ mpicc -showme
result :
gcc -I/Users/<USER_NAME>/openmpi-2.0.1/include -L/Users/<USER_NAME>/openmpi-2.0.1/lib -lmp
This command shows you the necessary libraries to compile mpicc
Example:
$ mpicc -g -I/Users/<USER_NAME>/openmpi-2.0.1/include -o [nameExec] [objetcs.o...] [program.c] -lm
$ mpicc -g -I/Users/<USER_NAME>/openmpi-2.0.1/include -o example file_object.o my_program.c otherlib.o -lm
this command generates executable with your program in example, you can execute :
$ ./example