NOTE: For a concise and efficient solution, please see Marc-André Lafortune's answer below.
This answer was originally offered as an alternative to approaches using flatten, which were the most highly upvoted at the time of writing. I should have clarified that I didn't intend to present this example as a best practice or an efficient approach. Original answer follows.
Warning! Solutions using flatten will not preserve Array keys or values!
Building on @John Topley's popular answer, let's try:
a3 = [ ['apple', 1], ['banana', 2], [['orange','seedless'], 3] ]
h3 = Hash[*a3.flatten]
This throws an error:
ArgumentError: odd number of arguments for Hash
from (irb):10:in `[]'
from (irb):10
The constructor was expecting an Array of even length (e.g. ['k1','v1,'k2','v2']). What's worse is that a different Array which flattened to an even length would just silently give us a Hash with incorrect values.
If you want to use Array keys or values, you can use map:
h3 = Hash[a3.map {|key, value| [key, value]}]
puts "h3: #{h3.inspect}"
This preserves the Array key:
h3: {["orange", "seedless"]=>3, "apple"=>1, "banana"=>2}