You can get the current username on Windows by going through the Windows API, although it's a bit cumbersome to invoke via the ctypes FFI (GetCurrentProcess ? OpenProcessToken ? GetTokenInformation ? LookupAccountSid).
I wrote a small module that can do this straight from Python, getuser.py. Usage:
import getuser
print(getuser.lookup_username())
It works on both Windows and *nix (the latter uses the pwd
module as described in the other answers).