If it is OK to use .NET code I'd suggest using SMO: http://msdn.microsoft.com/en-us/library/ms162169.aspx, In your particular case it would be the Table class http://msdn.microsoft.com/en-us/library/microsoft.sqlserver.management.smo.table.aspx This would be a more portable solution than using version specific system views and tables.
If this is something you are going to use on a regular basis - you might want to write a simple console application, perhaps with a runtime T4 code generator http://msdn.microsoft.com/en-us/library/ee844259.aspx
If it's just a one-off task - you could use my LiveDoco's( http://www.livedoco.com ) export to XML feature with an optional XSLT transform or I'm sure there are free tools out there that can do this. This one looks okay: http://sqldbdoc.codeplex.com/ - supports XML via XSLT, but I'm not sure if you can run it for a selection of tables though (With LiveDoco you can).