We had the same problem and this is the solution:
To force entity framework to use a column as a primary key, use ISNULL.
To force entity framework not to use a column as a primary key, use NULLIF.
An easy way to apply this is to wrap the select statement of your view in another select.
Example:
SELECT
ISNULL(MyPrimaryID,-999) MyPrimaryID,
NULLIF(AnotherProperty,'') AnotherProperty
FROM ( ... ) AS temp