While I agree with the others that you should not want it I'll just briefly explain what you can do to make a small difference without going all the way and actually blocking content that is already there -- maybe this will be enough to keep both you and your visitors happy.
The browser starts loading a page and will process externally located css and js later, especially if the place the css/js is linked is at the 'correct' place. (I think the advice is to load js as late as possible, and to use external css that you load in the header). Now if you have some portion of your css and/or js that you would like to be applied as soon as possible simply include that in the page itself. This will be against the advice of performance tools like YSlow but it probably will increase the change of your page showing up like you want it to be shown. Use this only when really needed!