To get around this issue, wrap your select statement in a CTE, and then you can query against the CTE and use the windowed function's results in the where clause.
WITH MyCte AS
(
select employee_id,
RowNum = row_number() OVER ( order by employee_id )
from V_EMPLOYEE
ORDER BY Employee_ID
)
SELECT employee_id
FROM MyCte
WHERE RowNum > 0