[regex] Regular expression negative lookahead

If you revise your regular expression like this:

drupal-6.14/(?=sites(?!/all|/default)).*
             ^^

...then it will match all inputs that contain drupal-6.14/ followed by sites followed by anything other than /all or /default. For example:

drupal-6.14/sites/foo
drupal-6.14/sites/bar
drupal-6.14/sitesfoo42
drupal-6.14/sitesall

Changing ?= to ?! to match your original regex simply negates those matches:

drupal-6.14/(?!sites(?!/all|/default)).*
             ^^

So, this simply means that drupal-6.14/ now cannot be followed by sites followed by anything other than /all or /default. So now, these inputs will satisfy the regex:

drupal-6.14/sites/all
drupal-6.14/sites/default
drupal-6.14/sites/all42

But, what may not be obvious from some of the other answers (and possibly your question) is that your regex will also permit other inputs where drupal-6.14/ is followed by anything other than sites as well. For example:

drupal-6.14/foo
drupal-6.14/xsites

Conclusion: So, your regex basically says to include all subdirectories of drupal-6.14 except those subdirectories of sites whose name begins with anything other than all or default.