This should do it:
^/\b([a-z0-9]+)\b(?<!ignoreme|ignoreme2|ignoreme3)
You can add as much ignored words as you like, here is a simple PHP implementation:
$ignoredWords = array('ignoreme', 'ignoreme2', 'ignoreme...');
preg_match('~^/\b([a-z0-9]+)\b(?<!' . implode('|', array_map('preg_quote', $ignoredWords)) . ')~i', $string);