Matthew's answer is correct:
list.get(0);
To do what you tried:
list[0];
you'll have to wait until Java 7 is released:
devoxx conference http://img718.imageshack.us/img718/11/capturadepantalla201003cg.png
Here's an interesting presentation by Mark Reinhold about Java 7
It looks like parleys site is currently down, try later :(