[asp.net] IIS URL Rewrite and Web.config

I don't understand anything about IIS, but am trying to solve this problem of redirecting all visitors to domain.com/page to domain.com/page.html

<?xml version="1.0" encoding="utf-8" ?>
<configuration>
  <system.webServer>
    <rewrite>
          <rewriteMaps>
              <rewriteMap name="StaticRedirects">
                  <add key="/page" value="/page.html" />
              </rewriteMap>
            </rewriteMaps>
      </rewrite>
  </system.webServer>
</configuration>

A couple of problems arise:

1. I don't know where to even put the file. There is a User root directory, and an htdocs directory, I tried both, no joy.
2. I don't even know if the account can do rewrites, I am trying to find that out.

Just wanted to point out one thing missing in LazyOne's answer (I would have just commented under the answer but don't have enough rep)

In rule #2 for permanent redirect there is thing missing:

redirectType="Permanent"

So rule #2 should look like this:

<system.webServer>
    <rewrite>
        <rules>
            <rule name="SpecificRedirect" stopProcessing="true">
                <match url="^page$" />
                <action type="Redirect" url="/page.html" redirectType="Permanent" />
            </rule>
        </rules>
    </rewrite>
</system.webServer>

Edit

For more information on how to use the URL Rewrite Module see this excellent documentation: URL Rewrite Module Configuration Reference

In response to @kneidels question from the comments; To match the url: topic.php?id=39 something like the following could be used:

<system.webServer>
  <rewrite>
    <rules>
      <rule name="SpecificRedirect" stopProcessing="true">
        <match url="^topic.php$" />
        <conditions logicalGrouping="MatchAll">
          <add input="{QUERY_STRING}" pattern="(?:id)=(\d{2})" />
        </conditions>
        <action type="Redirect" url="/newpage/{C:1}" appendQueryString="false" redirectType="Permanent" />
      </rule>
    </rules>
  </rewrite>
</system.webServer>

This will match topic.php?id=ab where a is any number between 0-9 and b is also any number between 0-9. It will then redirect to /newpage/xy where xy comes from the original url. I have not tested this but it should work.

Just tried this rule, and it worked with GoDaddy hosting since they've already have the Microsoft URL Rewriting module installed for every IIS 7 account.

<rewrite>
  <rules>
    <rule name="enquiry" stopProcessing="true">
      <match url="^enquiry$" />
      <action type="Rewrite" url="/Enquiry.aspx" />
    </rule>
  </rules>
</rewrite>