Couple of ways using count
or sum
In [338]: df
Out[338]:
col1 education
0 a 9th
1 b 9th
2 c 8th
In [335]: df.loc[df.education == '9th', 'education'].count()
Out[335]: 2
In [336]: (df.education == '9th').sum()
Out[336]: 2
In [337]: df.query('education == "9th"').education.count()
Out[337]: 2