Much simpler solution:
pd.DataFrame(df2["teams"].to_list(), columns=['team1', 'team2'])
Yields,
team1 team2
-------------
0 SF NYG
1 SF NYG
2 SF NYG
3 SF NYG
4 SF NYG
5 SF NYG
6 SF NYG
7 SF NYG
If you wanted to split a column of delimited strings rather than lists, you could similarly do:
pd.DataFrame(df["teams"].str.split('<delim>', expand=True).values,
columns=['team1', 'team2'])