[sql] ORA-00918: column ambiguously defined in SELECT *

You can also see this error when selecting for a union where corresponding columns can be null.

select * from (select D.dept_no, D.nullable_comment
                  from dept D
       union
               select R.dept_no, NULL
                 from redundant_dept R
)

This apparently confuses the parser, a solution is to assign a column alias to the always null column.

select * from (select D.dept_no, D.comment
                  from dept D
       union
               select R.dept_no, NULL "nullable_comment"
                 from redundant_dept R
)

The alias does not have to be the same as the corresponding column, but the column heading in the result is driven by the first query from among the union members, so it's probably a good practice.