If you wish to create a new schema in XE, you need to create an USER and assign its privileges. Follow these steps:
SQL> connect sys as sysdba
SQL> CREATE USER myschema IDENTIFIED BY Hga&dshja;
SQL> ALTER USER myschema QUOTA unlimited ON SYSTEM;
SQL> GRANT CREATE SESSION, CONNECT, RESOURCE, DBA TO myschema;
SQL> GRANT ALL PRIVILEGES TO myschema;
Now you can connect via Oracle SQL Developer and create your tables.