What I would do is run the loop until the ans is Q
ans=(R)
while not ans=='Q':
print('Your score is so far '+str(myScore)+'.')
print("Would you like to roll or quit?")
ans=input("Roll...")
if ans=='R':
R=random.randint(1, 8)
print("You rolled a "+str(R)+".")
myScore=R+myScore