First of all I'd like to say that I 100% agree with John Saunders that you must avoid loops in SQL in most cases especially in production.
But occasionally as a one time thing to populate a table with a hundred records for testing purposes IMHO it's just OK to indulge yourself to use a loop.
For example in your case to populate your table with records with hospital ids between 16 and 100 and make emails and descriptions distinct you could've used
CREATE PROCEDURE populateHospitals
AS
DECLARE @hid INT;
SET @hid=16;
WHILE @hid < 100
BEGIN
INSERT hospitals ([Hospital ID], Email, Description)
VALUES(@hid, 'user' + LTRIM(STR(@hid)) + '@mail.com', 'Sample Description' + LTRIM(STR(@hid)));
SET @hid = @hid + 1;
END
And result would be
ID Hospital ID Email Description
---- ----------- ---------------- ---------------------
1 16 [email protected] Sample Description16
2 17 [email protected] Sample Description17
...
84 99 [email protected] Sample Description99