The output of ps aux
looks like you did not start docker through systemd/systemctl.
It looks like you started it with:
sudo dockerd -H gridsim1103:2376
When you try to stop it with systemctl, nothing should happen as the resulting dockerd process is not controlled by systemd. So the behavior you see is expected.
The correct way to start docker is to use systemd/systemctl:
systemctl enable docker
systemctl start docker
After this, docker should start on system start.
EDIT: As you already have the docker process running, simply kill it by pressing CTRL+C on the terminal you started it. Or send a kill signal to the process.