Extending your code (assuming that the XML you want to send is in xmlString) :
String xmlString = "</xml>";
DefaultHttpClient httpClient = new DefaultHttpClient();
HttpPost httpRequest = new HttpPost(this.url);
httpRequest.setHeader("Content-Type", "application/xml");
StringEntity xmlEntity = new StringEntity(xmlString);
httpRequest.setEntity(xmlEntity );
HttpResponse httpresponse = httpclient.execute(httppost);